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Copper-Catalyzed Carboxylation of Aryl Iodides with Carbon Dioxide

A method for carboxylation of aryl iodides with carbon dioxide has been developed. The reaction employs low loadings of copper iodide/TMEDA or DMEDA catalyst, 1 atm of CO(2), DMSO or DMA solvent, and proceeds at 25–70 °C. Good functional group tolerance is observed, with ester, bromide, chloride, fl...

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Autors principals: Tran-Vu, Hung, Daugulis, Olafs
Format: Artigo
Idioma:Inglês
Publicat: 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3839347/
https://ncbi.nlm.nih.gov/pubmed/24288654
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cs400443p
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