Catalytic Enantioselective [2,3]-Rearrangements of Allylic Ammonium Ylides: A Mechanistic and Computational Study

[Image: see text] A mechanistic study of the isothiourea-catalyzed enantioselective [2,3]-rearrangement of allylic ammonium ylides is described. Reaction kinetic analyses using (19)F NMR and density functional theory computations have elucidated a reaction profile and allowed identification of the c...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: West, Thomas H., Walden, Daniel M., Taylor, James E., Brueckner, Alexander C., Johnston, Ryne C., Cheong, Paul Ha-Yeon, Lloyd-Jones, Guy C., Smith, Andrew D.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2017
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5374492/
https://ncbi.nlm.nih.gov/pubmed/28230365
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11851
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