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Stereoselective [2,3]-Sigmatropic Rearrangements of Unstabilized Nitrogen Ylides

[Image: see text] The steric course of the [2,3]-rearrangement of several unstabilized nitrogen ylides has been investigated. The reactions proceed cleanly through an anti transition state, affording modest to good yields of a single diastereomer of the product. In two examples containing an N-cinna...

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Hlavní autoři: Gawley, Robert E., Moon, Kwangyul
Médium: Artigo
Jazyk:Inglês
Vydáno: 2007
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2518686/
https://ncbi.nlm.nih.gov/pubmed/17628071
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol071188v
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