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Stereoselective [2,3]-Sigmatropic Rearrangements of Unstabilized Nitrogen Ylides
[Image: see text] The steric course of the [2,3]-rearrangement of several unstabilized nitrogen ylides has been investigated. The reactions proceed cleanly through an anti transition state, affording modest to good yields of a single diastereomer of the product. In two examples containing an N-cinna...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2007
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2518686/ https://ncbi.nlm.nih.gov/pubmed/17628071 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol071188v |
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