Thermolysis of Iso-Migrastatin and Its Congeners via [3,3]-Sigmatropic Rearrangement: A New Route to the Synthesis of Migrastatin and Its Analogues

[Image: see text] Thermolysis of iso-migrastatin (1) under neat heating conditions afforded migrastatin (1a). The reaction is proposed to proceed via a concerted [3,3]-sigmatropic rearrangement by which ring expansion is achieved regio- and enantio-specifically. The general applicability of this rea...

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Hlavní autoři: Ju, Jianhua, Lim, Si-Kyu, Jiang, Hui, Seo, Jeong-Woo, Her, Yeng, Shen, Ben
Médium: Artigo
Jazyk:Inglês
Vydáno: 2006
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Article
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2555980/
https://ncbi.nlm.nih.gov/pubmed/17134292
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol062470p
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