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Mechanistic Studies on Au(I)-Catalyzed [3,3]-Sigmatropic Rearrangements using Cyclopropane Probes

A comparative study of the Au(I)-catalyzed [3,3]-sigmatropic rearrangement of propargylic esters and propargyl vinyl ethers is described. Stereochemically defined cyclopropanes are employed as mechanistic probes to provide new synthetic and theoretical data concerning the reversibility of this type...

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Bibliografiske detaljer
Main Authors: Mauleón, Pablo, Krinsky, Jamin L., Toste, F. Dean
Format: Artigo
Sprog:Inglês
Udgivet: 2009
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2666792/
https://ncbi.nlm.nih.gov/pubmed/19275228
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja900456m
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