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Divergent Reactivity in Pd-Catalyzed [3,3]-Sigmatropic Rearrangement of Allyloxy- and Propargyloxy-Indoles Revealed by Computation and Experiment
Detailed computational (DFT) studies of the palladium(II)-catalyzed Claisen rearrangement of 2-allyloxy- and propargyloxyindoles revealed an unexpected divergent mode of reactivity. Subsequent experimental kinetic isotope effects are in accord with the mechanism derived from the computations. The co...
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| 發表在: | Org Lett |
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| Main Authors: | , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2018
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6201310/ https://ncbi.nlm.nih.gov/pubmed/30295492 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b02864 |
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