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Divergent Reactivity in Pd-Catalyzed [3,3]-Sigmatropic Rearrangement of Allyloxy- and Propargyloxy-Indoles Revealed by Computation and Experiment

Detailed computational (DFT) studies of the palladium(II)-catalyzed Claisen rearrangement of 2-allyloxy- and propargyloxyindoles revealed an unexpected divergent mode of reactivity. Subsequent experimental kinetic isotope effects are in accord with the mechanism derived from the computations. The co...

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Bibliografiske detaljer
Udgivet i:Org Lett
Main Authors: Gutierrez, Osvaldo, Hendrick, Charles E., Kozlowski, Marisa C.
Format: Artigo
Sprog:Inglês
Udgivet: 2018
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6201310/
https://ncbi.nlm.nih.gov/pubmed/30295492
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b02864
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