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Intercepting fleeting cyclic allenes with asymmetric nickel catalysis

Strained cyclic organic molecules, such as arynes, cyclic alkynes and cyclic allenes, have intrigued chemists for more than a century with their unusual structures and high chemical reactivity(1). The considerable ring strain (30–50 kilocalories per mole)(2,3) that characterizes these transient inte...

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Dades bibliogràfiques
Publicat a:Nature
Autors principals: Yamano, Michael M., Kelleghan, Andrew V., Shao, Qianzhen, Giroud, Maude, Simmons, Bryan J., Li, Bo, Chen, Shuming, Houk, K. N., Garg, Neil K.
Format: Artigo
Idioma:Inglês
Publicat: 2020
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8297713/
https://ncbi.nlm.nih.gov/pubmed/32846425
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41586-020-2701-2
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