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Origins of Endo Selectivity in Diels–Alder Reactions of Cyclic Allene Dienophiles

Strained cyclic allenes, first discovered in 1966 by Wittig and coworkers, have recently emerged as valuable synthetic building blocks. Previous experimental investigations, and computations reported here, demonstrate that the Diels–Alder reactions of furans and pyrroles to 1,2-cyclohexadiene and ox...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Ramirez, Melissa, Svatunek, Dennis, Liu, Fang, Garg, Neil K., Houk, K. N.
Formato: Artigo
Idioma:Inglês
Publicado em: 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8217342/
https://ncbi.nlm.nih.gov/pubmed/33851504
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202101809
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