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Origins of the Endo and Exo Selectivities in Cyclopropenone, Iminocyclopropene, and Triafulvene Diels-Alder Cycloadditions
The endo and exo stereoselectivities of Diels—Alder reactions of cyclopropenone, iminocyclopropene, and substituted triafulvenes with butadiene were rationalized using density functional theory calculations. When cyclopropenone is the dienophile, there is a 1.8 kcal/mol preference for the exo cycloa...
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| Опубликовано в: : | J Org Chem |
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| Главные авторы: | , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2018
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6314817/ https://ncbi.nlm.nih.gov/pubmed/29470085 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.8b00025 |
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