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The simplest Diels–Alder reactions are not endo-selective

There is a widespread perception that the high level of endo selectivity witnessed in many Diels–Alder reactions is an intrinsic feature of the transformation. In contrast to expectations based upon this existing belief, the first experimental Diels–Alder reactions of a novel, deuterium-labeled 1,3-...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Lording, William J., Fallon, Thomas, Sherburn, Michael S., Paddon-Row, Michael N.
Format: Artigo
Langue:Inglês
Publié: The Royal Society of Chemistry 2020
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162770/
https://ncbi.nlm.nih.gov/pubmed/34123213
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04553e
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