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Chiral allene-containing phosphines in asymmetric catalysis

Traditionally, ligands used in asymmetric catalysis have contained either stereogenic atoms or hindered single bonds (atropisomerism), or both. Here we demonstrate that allenes, chiral 1,2-dienes, appended with basic functionality can serve as ligands for transition metals. We describe an allene-con...

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Détails bibliographiques
Auteurs principaux: Cai, Feng, Pu, Xiaotao, Qi, Xiangbing, Lynch, Vincent, Radha, Akella, Ready, Joseph M.
Format: Artigo
Langue:Inglês
Publié: 2011
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3216402/
https://ncbi.nlm.nih.gov/pubmed/21972824
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja207748r
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