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Chiral allene-containing phosphines in asymmetric catalysis
Traditionally, ligands used in asymmetric catalysis have contained either stereogenic atoms or hindered single bonds (atropisomerism), or both. Here we demonstrate that allenes, chiral 1,2-dienes, appended with basic functionality can serve as ligands for transition metals. We describe an allene-con...
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| Hlavní autoři: | , , , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2011
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3216402/ https://ncbi.nlm.nih.gov/pubmed/21972824 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja207748r |
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