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Allenes in Asymmetric Catalysis. Asymmetric Ring-Opening of Meso-Epoxides Catalyzed by Allene-Containing Phosphine Oxides

Unsymmetrically substituted allenes (1,2 dienes) are inherently chiral and can be prepared in optically pure form. Nonetheless, to date the allene framework has not been incorporated into ligands for asymmetric catalysis. Since allenes project functionality differently than either tetrahedral carbon...

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Main Authors: Pu, Xiaotao, Qi, Xiangbing, Ready, Joseph M.
Format: Artigo
Jezik:Inglês
Izdano: 2009
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2760382/
https://ncbi.nlm.nih.gov/pubmed/19722613
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9041127
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