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Allenes in Asymmetric Catalysis. Asymmetric Ring-Opening of Meso-Epoxides Catalyzed by Allene-Containing Phosphine Oxides

Unsymmetrically substituted allenes (1,2 dienes) are inherently chiral and can be prepared in optically pure form. Nonetheless, to date the allene framework has not been incorporated into ligands for asymmetric catalysis. Since allenes project functionality differently than either tetrahedral carbon...

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Autors principals: Pu, Xiaotao, Qi, Xiangbing, Ready, Joseph M.
Format: Artigo
Idioma:Inglês
Publicat: 2009
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2760382/
https://ncbi.nlm.nih.gov/pubmed/19722613
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9041127
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