Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands
A library of chiral Schiff base ligands was synthesizedfrom aromatic aldehydes and chiral amino alcohols. These ligandswere then screened as catalysts in the asymmetric ring opening ofmeso-cyclohexene epoxide with phenyllithium to give (1S,2R)-phenylcyclohexanol in 9-67% ee.
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| Publicado en: | Journal of the Mexican Chemical Society |
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| Principais autores: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Sociedad Química de México
2004
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| Assuntos: | |
| Acceso en liña: | https://www.redalyc.org/articulo.oa?id=47548111 |
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