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Intercepting fleeting cyclic allenes with asymmetric nickel catalysis
Strained cyclic organic molecules, such as arynes, cyclic alkynes and cyclic allenes, have intrigued chemists for more than a century with their unusual structures and high chemical reactivity(1). The considerable ring strain (30–50 kilocalories per mole)(2,3) that characterizes these transient inte...
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| Publicado no: | Nature |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8297713/ https://ncbi.nlm.nih.gov/pubmed/32846425 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41586-020-2701-2 |
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