Synthesis of Pyrroles via Consecutive 6π-Electrocyclization/Ring-Contraction of Sulfilimines

[Image: see text] We present a modular, synthetic entry to polysubstituted pyrroles employing readily available 2,5-dihydrothiophenes. Ring-opening of the heterocycle provides access to a panel of 1,3-dienes which undergo pyrrole formation in the presence of inexpensive chloramine-T trihydrate. The...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Haut, Franz-Lucas, Feichtinger, Niklas J., Plangger, Immanuel, Wein, Lukas A., Müller, Mira, Streit, Tim-Niclas, Wurst, Klaus, Podewitz, Maren, Magauer, Thomas
Format: Artigo
Language:Inglês
Published: American Chemical Society 2021
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8227482/
https://ncbi.nlm.nih.gov/pubmed/34106724
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c04835
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