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A Divergent Polyene Cyclization for the Total Synthesis of Greenwayodendrines, Greenwaylactams, Polysin and Polyveoline
We present a concise (5–8 steps) asymmetric total synthesis of nine sesquiterpenoid alkaloids featuring four different tetra-/pentacyclic scaffolds. To this end, a novel, bioinspired indole N-terminated cationic tricyclization has been developed enabling the divergent synthesis of greenwayodendrines...
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| Izdano u: | Angew Chem Int Ed Engl |
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| Glavni autori: | , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2023
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7614870/ https://ncbi.nlm.nih.gov/pubmed/37318945 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202307719 |
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