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Total Synthesis and Late‐Stage C−H Oxidations of ent‐Trachylobane Natural Products
Herein, we present our studies to construct seven ent‐trachylobane diterpenoids by employing a bioinspired two‐phase synthetic strategy. The first phase provided enantioselective and scalable access to five ent‐trachylobanes, of which methyl ent‐trachyloban‐19‐oate was produced on a 300 mg scale. Du...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7612322/ https://ncbi.nlm.nih.gov/pubmed/34762359 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202113829 |
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