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Synthesis of (–)-Mitrephorone A via a Bio-inspired Late Stage C–H Oxidation of (–)-Mitrephorone B
We present a bio-inspired late stage C–H oxidation of the ent-trachylobane natural product mitrephorone B to mitrephorone A. The realization of this unprecedented transformation was accomplished by either an iron-catalyzed or electrochemical oxidation and enabled access to the densely substituted ox...
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| Vydáno v: | J Am Chem Soc |
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| Hlavní autoři: | , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2019
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6946608/ https://ncbi.nlm.nih.gov/pubmed/31770485 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b11646 |
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