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Synthesis of Vicinal Quaternary All-Carbon Centers via Acid-catalyzed Cycloisomerization of Neopentylic Epoxides
[Image: see text] We report our studies on the development of a catalytic cycloisomerization of 2,2-disubstituted neopentylic epoxides to produce highly substituted tetralins and chromanes. Termination of the sequence occurs via Friedel–Crafts-type alkylation of the remote (hetero)arene linker. The...
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| Publicado no: | Org Lett |
|---|---|
| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2020
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7115968/ https://ncbi.nlm.nih.gov/pubmed/32806198 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c02296 |
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