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Bio-inspired iron-catalyzed oxidation of alkylarenes enables late-stage oxidation of complex methylarenes to arylaldehydes

It is a long-standing challenge to achieve efficient and highly selective aerobic oxidation of methylarenes to benzaldehydes, owing to overoxidation problem stemming from the oxidizability of benzaldehyde far higher than the toluene under usual aerobic conditions. Herein we report a bio-inspired iro...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Hu, Penghui, Tan, Mingxi, Cheng, Lu, Zhao, Hongyuan, Feng, Rui, Gu, Wei-Jin, Han, Wei
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6546739/
https://ncbi.nlm.nih.gov/pubmed/31160563
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-10414-7
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