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Bio-inspired iron-catalyzed oxidation of alkylarenes enables late-stage oxidation of complex methylarenes to arylaldehydes

It is a long-standing challenge to achieve efficient and highly selective aerobic oxidation of methylarenes to benzaldehydes, owing to overoxidation problem stemming from the oxidizability of benzaldehyde far higher than the toluene under usual aerobic conditions. Herein we report a bio-inspired iro...

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Dades bibliogràfiques
Publicat a:Nat Commun
Autors principals: Hu, Penghui, Tan, Mingxi, Cheng, Lu, Zhao, Hongyuan, Feng, Rui, Gu, Wei-Jin, Han, Wei
Format: Artigo
Idioma:Inglês
Publicat: Nature Publishing Group UK 2019
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6546739/
https://ncbi.nlm.nih.gov/pubmed/31160563
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-10414-7
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