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Bio-inspired iron-catalyzed oxidation of alkylarenes enables late-stage oxidation of complex methylarenes to arylaldehydes

It is a long-standing challenge to achieve efficient and highly selective aerobic oxidation of methylarenes to benzaldehydes, owing to overoxidation problem stemming from the oxidizability of benzaldehyde far higher than the toluene under usual aerobic conditions. Herein we report a bio-inspired iro...

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Pubblicato in:Nat Commun
Autori principali: Hu, Penghui, Tan, Mingxi, Cheng, Lu, Zhao, Hongyuan, Feng, Rui, Gu, Wei-Jin, Han, Wei
Natura: Artigo
Lingua:Inglês
Pubblicazione: Nature Publishing Group UK 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6546739/
https://ncbi.nlm.nih.gov/pubmed/31160563
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-10414-7
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