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Collaborative Total Synthesis: Routes to (±)-Hippolachnin A Enabled by Quadricyclane Cycloaddition and Late-Stage C–H Oxidation

Described herein are synthetic efforts toward the synthesis of hippolachnin A. Two independently devised routes from the Brown and Wood groups allowed for the synthesis of hippolachnin A from the unusual starting material, quadricyclane, by harnessing the power of late-stage C–H oxidation. Collabora...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: McCallum, Monica E., Rasik, Christopher M., Wood, John L., Brown, M. Kevin
Format: Artigo
Sprog:Inglês
Udgivet: 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4866603/
https://ncbi.nlm.nih.gov/pubmed/26859526
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b13586
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