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A Transannular Polyene Tetracyclization for Rapid Construction of the Pimarane Framework

Polyene cyclizations are one of the most powerful and fascinating chemical transformations to rapidly generate molecular complexity. However, cyclizations employing heteroatom‐substituted polyenes are rare. Described here is the tetracyclization of a dual nucleophilic aryl enol ether involving an un...

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發表在:Angew Chem Int Ed Engl
Main Authors: Feilner, Julian M., Wurst, Klaus, Magauer, Thomas
格式: Artigo
語言:Inglês
出版: John Wiley and Sons Inc. 2020
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC7383491/
https://ncbi.nlm.nih.gov/pubmed/32167649
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202003127
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