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Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms
Allylation of nucleophiles with highly reactive electrophiles like allyl halides can be conducted without metal catalysts. Less reactive electrophiles, such as allyl esters and carbonates, usually require a transition metal catalyst to facilitate the allylation. Herein, we report a unique transition...
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| Publicado no: | Nat Commun |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Nature Publishing Group UK
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8222226/ https://ncbi.nlm.nih.gov/pubmed/34162867 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-24027-6 |
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