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Transition-Metal-Free Radical C(sp(3))–C(sp(2)) and C(sp(3))–C(sp(3)) Coupling Enabled by 2-Azaallyls as Super-Electron-Donors and Coupling-Partners

The past decade has witnessed the rapid development of radical generation strategies and their applications in C–C bond-forming reactions. Most of these processes require initiators, transition metal catalysts or organometallic reagents. Herein, we report the discovery of a simple organic system (2-...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Li, Minyan, Berritt, Simon, Matuszewski, Lucas, Deng, Guogang, Pascual-Escudero, Ana, Panetti, Grace B., Poznik, Michal, Yang, Xiaodong, Chruma, Jason J., Walsh, Patrick J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5737768/
https://ncbi.nlm.nih.gov/pubmed/29019654
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b09394
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