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Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms

Allylation of nucleophiles with highly reactive electrophiles like allyl halides can be conducted without metal catalysts. Less reactive electrophiles, such as allyl esters and carbonates, usually require a transition metal catalyst to facilitate the allylation. Herein, we report a unique transition...

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Vydáno v:Nat Commun
Hlavní autoři: Deng, Guogang, Duan, Shengzu, Wang, Jing, Chen, Zhuo, Liu, Tongqi, Chen, Wen, Zhang, Hongbin, Yang, Xiaodong, Walsh, Patrick J.
Médium: Artigo
Jazyk:Inglês
Vydáno: Nature Publishing Group UK 2021
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8222226/
https://ncbi.nlm.nih.gov/pubmed/34162867
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-24027-6
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