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Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms

Allylation of nucleophiles with highly reactive electrophiles like allyl halides can be conducted without metal catalysts. Less reactive electrophiles, such as allyl esters and carbonates, usually require a transition metal catalyst to facilitate the allylation. Herein, we report a unique transition...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Nat Commun
Prif Awduron: Deng, Guogang, Duan, Shengzu, Wang, Jing, Chen, Zhuo, Liu, Tongqi, Chen, Wen, Zhang, Hongbin, Yang, Xiaodong, Walsh, Patrick J.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Nature Publishing Group UK 2021
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC8222226/
https://ncbi.nlm.nih.gov/pubmed/34162867
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-24027-6
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