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Transition‐Metal‐Free Borylation of Allylic and Propargylic Alcohols

The base‐catalyzed allylic borylation of tertiary allylic alcohols allows the synthesis of 1,1‐disubstituted allyl boronates, in moderate to high yield. The unexpected tandem performance of the Lewis acid–base adduct, [Hbase](+)[MeO‐B(2)pin(2)](−) favored the formation of 1,2,3‐triborylated species...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Miralles, Núria, Alam, Rauful, Szabó, Kálmán J., Fernández, Elena
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2016
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Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC4804746/
https://ncbi.nlm.nih.gov/pubmed/26934578
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511255
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