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Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine, and Oxetane Substrates: Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates

A new copper‐catalyzed reaction for the stereo‐ and regioselective synthesis of alkenyl diboronates and allenyl boronates is presented. In this process propargyl derivatives of strained three/four‐membered rings were employed as substrates and B(2)pin(2) was used as the boronate source. Selective fo...

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Detalles Bibliográficos
Publicado en:Angew Chem Int Ed Engl
Main Authors: Zhao, Jian, Szabó, Kálmán J.
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2015
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC4736465/
https://ncbi.nlm.nih.gov/pubmed/26663468
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201510132
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