Catalytic, Enantioselective Synthesis of Allenyl Boronates

A method to achieve enantioselective 1,4-hydroboration of terminal enynes to access allenyl boronates under CuH catalysis is described. The reaction typically proceeds in a highly stereoselective manner and tolerates an array of synthetically useful functional groups. The utility of the enantioenric...

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發表在:ACS Catal
Main Authors: Gao, De-Wei, Xiao, Yiyang, Liu, Mingyu, Liu, Zhen, Karunananda, Malkanthi K., Chen, Jason S., Engle, Keary M.
格式: Artigo
語言:Inglês
出版: 2018
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Article
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC6364988/
https://ncbi.nlm.nih.gov/pubmed/30740261
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.8b00626
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