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Transition‐Metal‐Free Borylation of Allylic and Propargylic Alcohols

The base‐catalyzed allylic borylation of tertiary allylic alcohols allows the synthesis of 1,1‐disubstituted allyl boronates, in moderate to high yield. The unexpected tandem performance of the Lewis acid–base adduct, [Hbase](+)[MeO‐B(2)pin(2)](−) favored the formation of 1,2,3‐triborylated species...

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Bibliografski detalji
Izdano u:Angew Chem Int Ed Engl
Glavni autori: Miralles, Núria, Alam, Rauful, Szabó, Kálmán J., Fernández, Elena
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2016
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4804746/
https://ncbi.nlm.nih.gov/pubmed/26934578
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201511255
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