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Metal‐Free Radical Borylation of Alkyl and Aryl Iodides

A metal‐free radical borylation of alkyl and aryl iodides with bis(catecholato)diboron (B(2)cat(2)) as the boron source under mild conditions is introduced. The borylation reaction is operationally easy to conduct and shows high functional group tolerance and broad substrate scope. Radical clock exp...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Cheng, Ying, Mück‐Lichtenfeld, Christian, Studer, Armido
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2018
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6470957/
https://ncbi.nlm.nih.gov/pubmed/30332527
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201810782
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