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Metal‐Free Radical Borylation of Alkyl and Aryl Iodides

A metal‐free radical borylation of alkyl and aryl iodides with bis(catecholato)diboron (B(2)cat(2)) as the boron source under mild conditions is introduced. The borylation reaction is operationally easy to conduct and shows high functional group tolerance and broad substrate scope. Radical clock exp...

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Publicado en:Angew Chem Int Ed Engl
Main Authors: Cheng, Ying, Mück‐Lichtenfeld, Christian, Studer, Armido
Formato: Artigo
Idioma:Inglês
Publicado: John Wiley and Sons Inc. 2018
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6470957/
https://ncbi.nlm.nih.gov/pubmed/30332527
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201810782
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