Photoexcited Pd(ii) auxiliaries enable light-induced control in C(sp(3))–H bond functionalisation

Herein we report the photophysical and photochemical properties of palladacycle complexes derived from 8-aminoquinoline ligands, commonly used auxiliaries in C–H activation. Spectroscopic, electrochemical and computational studies reveal that visible light irradiation induces a mixed LLCT/MLCT charg...

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Bibliografiske detaljer
Udgivet i:Chem Sci
Main Authors: Czyz, Milena L., Weragoda, Geethika K., Horngren, Tyra H., Connell, Timothy U., Gomez, Daniel, O'Hair, Richard A. J., Polyzos, Anastasios
Format: Artigo
Sprog:Inglês
Udgivet: The Royal Society of Chemistry 2020
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8157331/
https://ncbi.nlm.nih.gov/pubmed/34084410
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05722f
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