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General, Auxiliary-Enabled Photoinduced Pd-Catalyzed Remote Desaturation of Aliphatic Alcohols

A general, efficient, and site-selective visible light-induced Pd-catalyzed remote desaturation of aliphatic alcohols into valuable allylic, homoallylic, and bis-homoallylic alcohols has been developed. This transformation operates via a hybrid Pd-radical mechanism, which synergistically combines th...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Parasram, Marvin, Chuentragool, Padon, Wang, Yang, Shi, Yi, Gevorgyan, Vladimir
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5729750/
https://ncbi.nlm.nih.gov/pubmed/28992686
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b08459
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