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General, Mild, and Selective Method for Desaturation of Aliphatic Amines

A novel method for desaturation of aliphatic amines into enamines as well as allylic and homoallylic amines has been developed. This general protocol operates via putative aryl hybrid Pd-radical intermediates, which combine the signature features of radical chemistry, a hydrogen atom transfer (HAT)...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Chuentragool, Padon, Parasram, Marvin, Shi, Yi, Gevorgyan, Vladimir
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5821538/
https://ncbi.nlm.nih.gov/pubmed/29400959
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b00488
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