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Proton-Coupled Electron Transfer Reactivity Controls Iron Versus Sulfur Oxidation in Nonheme Iron Thiolate Complexes
Reaction of the 5-coordinate Fe(II)(N(4)S) complexes, [Fe(II)(iPr(3)TACN)(abt(x))](OTf) (abt = aminobenzenethiolate, X = H, CF(3)) with a one-electron oxidant and an appropriate base leads to net H-atom loss, generating new Fe(III)(iminobenzenethiolate) complexes that were characterized by single-cr...
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| I publikationen: | Inorg Chem |
|---|---|
| Huvudupphovsmän: | , , , |
| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2021
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8139613/ https://ncbi.nlm.nih.gov/pubmed/33872005 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.0c03779 |
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