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Highly regio- and stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditions

The homolytic cleavage of the P(V)(O)–P(III) bond in tetraphenyldiphosphine monoxide simultaneously provides both pentavalent and trivalent phosphorus-centered radicals with different reactivities. The method using V-40 as an initiator is successfully investigated for the regio- and stereoselective...

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Bibliografiske detaljer
Udgivet i:Beilstein J Org Chem
Main Authors: Tran, Dat Phuc, Sato, Yuki, Yamamoto, Yuki, Kawaguchi, Shin-ichi, Kodama, Shintaro, Nomoto, Akihiro, Ogawa, Akiya
Format: Artigo
Sprog:Inglês
Udgivet: Beilstein-Institut 2021
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8077611/
https://ncbi.nlm.nih.gov/pubmed/33968259
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.17.72
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