Highly regio- and stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditions

The homolytic cleavage of the P(V)(O)–P(III) bond in tetraphenyldiphosphine monoxide simultaneously provides both pentavalent and trivalent phosphorus-centered radicals with different reactivities. The method using V-40 as an initiator is successfully investigated for the regio- and stereoselective...

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Veröffentlicht in:Beilstein J Org Chem
Hauptverfasser: Tran, Dat Phuc, Sato, Yuki, Yamamoto, Yuki, Kawaguchi, Shin-ichi, Kodama, Shintaro, Nomoto, Akihiro, Ogawa, Akiya
Format: Artigo
Sprache:Inglês
Veröffentlicht: Beilstein-Institut 2021
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8077611/
https://ncbi.nlm.nih.gov/pubmed/33968259
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.17.72
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