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Highly regio- and stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditions
The homolytic cleavage of the P(V)(O)–P(III) bond in tetraphenyldiphosphine monoxide simultaneously provides both pentavalent and trivalent phosphorus-centered radicals with different reactivities. The method using V-40 as an initiator is successfully investigated for the regio- and stereoselective...
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| Publié dans: | Beilstein J Org Chem |
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| Auteurs principaux: | , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Beilstein-Institut
2021
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8077611/ https://ncbi.nlm.nih.gov/pubmed/33968259 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.17.72 |
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