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Highly regio- and stereoselective phosphinylphosphination of terminal alkynes with tetraphenyldiphosphine monoxide under radical conditions

The homolytic cleavage of the P(V)(O)–P(III) bond in tetraphenyldiphosphine monoxide simultaneously provides both pentavalent and trivalent phosphorus-centered radicals with different reactivities. The method using V-40 as an initiator is successfully investigated for the regio- and stereoselective...

詳細記述

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書誌詳細
出版年:Beilstein J Org Chem
主要な著者: Tran, Dat Phuc, Sato, Yuki, Yamamoto, Yuki, Kawaguchi, Shin-ichi, Kodama, Shintaro, Nomoto, Akihiro, Ogawa, Akiya
フォーマット: Artigo
言語:Inglês
出版事項: Beilstein-Institut 2021
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC8077611/
https://ncbi.nlm.nih.gov/pubmed/33968259
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.17.72
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