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A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity

The central role of cupric superoxide intermediates proposed in hormone and neurotransmitter biosynthesis by noncoupled binuclear copper monooxygenases like dopamine-β-monooxygenase has drawn significant attention to the unusual methionine ligation of the Cu(M) (“Cu(B)”) active site characteristic o...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Bhadra, Mayukh, Transue, Wesley J., Lim, Hyeongtaek, Cowley, Ryan E., Lee, Jung Yoon C., Siegler, Maxime A., Josephs, Patrick, Henkel, Gerald, Lerch, Markus, Schindler, Siegfried, Neuba, Adam, Hodgson, Keith O., Hedman, Britt, Solomon, Edward I., Karlin, Kenneth D.
Format: Artigo
Jezik:Inglês
Izdano: 2021
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC8023764/
https://ncbi.nlm.nih.gov/pubmed/33684290
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c00260
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