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Ligand-Enabled Pd(II)-Catalyzed C(sp(3))–H Lactonization using Molecular oxygen as oxidant

Pd(II)-catalyzed C–H lactonization of o-methyl benzoic acid substrates has been achieved using molecular oxygen as the oxidant. This finding provides a rare example of C–H oxygenation through Pd(II)/Pd(0) catalysis, as well as a method to construct biologically important benzolactone scaffolds. The...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Qian, Shaoqun, Li, Zi-Qi, Li, Minyan, Wisniewski, Steven R., Qiao, Jennifer X., Richter, Jeremy M., Ewing, William R., Eastgate, Martin D., Chen, Jason S., Yu, Jin-Quan
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8023385/
https://ncbi.nlm.nih.gov/pubmed/32330054
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.0c01243
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