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Transient Directing Group Enabled Pd-catalyzed γ-C(sp(3))–H Oxygenation of Alkyl Amines
We report a general protocol for γ-C(sp(3))–H acyloxylation and alkoxylation of free amines using 2-hydroxynicotinaldehyde as the transient directing group. In the presence of an electrophilic fluorinating bystanding oxidant and acetic acid, a wide range of aliphatic amines could be oxygenated selec...
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| Udgivet i: | ACS Catal |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8118595/ https://ncbi.nlm.nih.gov/pubmed/33996194 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.0c01310 |
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