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Pd-catalyzed γ-C(sp(3))–H Arylation of Free Amines Using a Transient Directing Group
Pd(II)-catalyzed γ-C(sp(3))–H arylation of primary amines is realized by using 2-hydroxynicotinaldehyde as a catalytic transient directing group. Importantly, the catalyst and the directing group loading can be lowered to 2% and 4% respectively, thus demonstrating high efficiency of this newly desig...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5535771/ https://ncbi.nlm.nih.gov/pubmed/27786439 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09653 |
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