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Pd-catalyzed γ-C(sp(3))–H Arylation of Free Amines Using a Transient Directing Group
Pd(II)-catalyzed γ-C(sp(3))–H arylation of primary amines is realized by using 2-hydroxynicotinaldehyde as a catalytic transient directing group. Importantly, the catalyst and the directing group loading can be lowered to 2% and 4% respectively, thus demonstrating high efficiency of this newly desig...
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| Vydáno v: | J Am Chem Soc |
|---|---|
| Hlavní autoři: | , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2016
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5535771/ https://ncbi.nlm.nih.gov/pubmed/27786439 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09653 |
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