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Diastereoselective Synthesis of 6″-(Z)- and 6″-(E)-Fluoro Analogues of Anti-hepatitis B Virus Agent Entecavir and Its Evaluation of the Activity and Toxicity Profile of the Diastereomers

A method for the diastereoselective synthesis of 6″-(Z)- and 6″-(E)-fluorinated analogues of the anti-HBV agent entecavir has been developed. Construction of the methylenecyclopentane skeleton of the target molecules has been accomplished by radical-mediated 5-exo-dig cyclization of the selenides 6...

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Dades bibliogràfiques
Publicat a:J Org Chem
Autors principals: Kumamoto, Hiroki, Fukano, Misato, Nakano, Tomohiko, Iwagami, Keito, Takeyama, Chiaki, Kohgo, Satoru, Imoto, Shuhei, Amano, Masayuki, Kuwata-Higashi, Nobuyo, Aoki, Manabu, Abe, Hiroshi, Mitsuya, Hiroaki, Fukuhara, Kiyoshi, Haraguchi, Kazuhiro
Format: Artigo
Idioma:Inglês
Publicat: 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC7821961/
https://ncbi.nlm.nih.gov/pubmed/27009432
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b00105
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