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pH-Dependent peptide bond formation by the selective coupling of α-amino acids in water
A novel mechanism enabling selective peptide elongation by coupling α-amino acids over other potentially competing prebiotic amines under acidic aqueous condition is suggested. It proceeds via the generation of a carboxylic acid anhydride intermediate with subsequent intramolecular formation of the...
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| Publicado no: | Chem Commun (Camb) |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7808311/ https://ncbi.nlm.nih.gov/pubmed/33242043 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0cc06042a |
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