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Scalable synthesis and coupling of quaternary α-arylated amino acids: α-aryl substituents are tolerated in α-helical peptides

Quaternary amino acids are important tools for the modification and stabilisation of peptide secondary structures. Here we describe a practical and scalable synthesis applicable to quaternary alpha-arylated amino acids (Q4As), and the development of solid-phase synthesis conditions for their incorpo...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Leonard, Daniel J., Zieleniewski, Francis, Wellhöfer, Isabelle, Baker, Emily G., Ward, John W., Woolfson, Derek N., Clayden, Jonathan
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8278958/
https://ncbi.nlm.nih.gov/pubmed/34349911
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01378e
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